Disc 1
1. "In the Heat of the Morning" 3:02
2. "London Bye Ta Ta" 2:36
3. "Karma Man" 3:00
4. "Silly Boy Blue" 6:08
Tracks 1 to 4 recorded for John Peel in Top Gear as "David Bowie and the Tony Visconti Orchestra," May 13, 1968 (1968-05-13), tracks 1-3 broadcast May 26, 1968 (1968-05-26).
5. "Let Me Sleep Beside You" 3:17
6. "Janine" 3:24
Tracks 5 and 6 recorded for D.L.T. (Dave Lee Travis Show) as "David Bowie and Junior's Eyes," October 20, 1969 (1969-10-20); neither track were broadcast.
7. "Amsterdam" 3:18
8. "God Knows I'm Good" 3:36
9. "The Width of a Circle" 5:21
10. "Unwashed and Somewhat Slightly Dazed" 5:07
11. "Cygnet Committee" 9:07
12. "Memory of a Free Festival" 3:18
Tracks 7 to 12 recorded for The Sunday Show introduced by John Peel as "David Bowie and the Tony Visconti Trio (aka The Hype)," February 5, 1970 (1970-02-05), broadcast date February 8, 1970 (1970-02-08).
13. "Wild Eyed Boy from Freecloud" 5:55
Track 13 recorded for Sounds Of The 70s: Andy Ferris as "David Bowie and the Tony Visconti Trio," March 25, 1970 (1970-03-25), broadcast date April 6, 1970 (1970-04-06).
14. "Bombers" 3:19
15. "Looking for a Friend" 3:34
16. "Almost Grown" (Chuck Berry) 2:44
17. "Kooks" 3:32
18. "It Ain't Easy" (Ron Davies) 2:51
Tracks 14 to 18 recorded for In Concert: John Peel as "David Bowie and friends," June 3, 1971 (1971-06-03), broadcast date June 20, 1971 (1971-06-20).
Disc 2
1. "The Supermen" 2:51
2. "Eight Line Poem" 2:56
Tracks 1 and 2 recorded for Sounds Of The 70s: Bob Harris by David Bowie with Mick Ronson, September 21, 1971 (1971-09-21), broadcast date October 4, 1971 (1971-10-04).
3. "Hang on to Yourself" 2:50
4. "Ziggy Stardust" 3:26
5. "Queen ~censored~" 2:59
6. "I'm Waiting for the Man" (Lou Reed) 5:24
7. "Five Years" 4:24
Tracks 3 to 7 recorded for Sounds Of The 70s: Bob Harris as "David Bowie and The Spiders from Mars", January 8, 1972 (1972-01-08), broadcast date February 7, 1972 (1972-02-07).
8. "White Light/White Heat" (Reed) 3:48
9. "Moonage Daydream" 4:58
10. "Hang on to Yourself" 2:50
11. "Suffragette City" 3:28
12. "Ziggy Stardust" 3:24
Tracks 8 to 12 recorded for Sounds Of The 70s: John Peel as "David Bowie and The Spiders from Mars," May 16, 1972 (1972-05-16), broadcast date May 23, 1972 (1972-05-23).
13. "Starman" 4:05
14. "Space Oddity" 4:16
15. "Changes" 3:29
16. "Oh! You Pretty Things" 2:57
Tracks 13 to 16 recorded for Johnnie Walker Lunchtime Show as "David Bowie and The Spiders from Mars," May 22, 1972 (1972-05-22), broadcast date June 5, 1972 (1972-06-05)June 9, 1972 (1972-06-09).
17. "Andy Warhol" 3:14
18. "Lady Stardust" 3:21
19. "Rock 'n' Roll Suicide" 3:08
Tracks 17 to 19 recorded for Sounds Of The 70s: Bob Harris as "David Bowie and The Spiders from Mars," May 23, 1972 (1972-05-23), broadcast date June 19, 1972 (1972-06-19).
Disc 3
Supplied as a bonus disc with 2000-release limited editions.
1. "Wild Is the Wind" (Ned Washington, Dimitri Tiomkin) 6:23
2. "Ashes to Ashes" 5:04
3. "Seven" (Bowie, Reeves Gabrels) 4:13
4. "This Is Not America" (Bowie, Pat Metheny, Lyle Mays) 3:44
5. "Absolute Beginners" 6:32
6. "Always Crashing in the Same Car" 4:07
7. "Survive" (Bowie, Gabrels) 4:55
8. "Little Wonder" (Bowie, Gabrels, Mark Plati) 3:49
9. "The Man Who Sold the World" 3:58
10. "Fame" (Bowie, Carlos Alomar, John Lennon) 4:12
11. "Stay" 5:45
12. "Hallo Spaceboy" (Bowie, Brian Eno) 5:22
13. "Cracked Actor" 4:10
14. "I'm Afraid of Americans" 5:30
15. "Let's Dance" 6:20